You're right but you'll get a better idea if you get a tds meter. Ec does tell you how much salts are dissolved in water yes, ive never been successful that way. Since I started measuring ppm and ph it seems like I have a lot less problems in soil.
In my experience ec is used by people that use ro water or something close where there is absolutely nothing in the water to begin with, but you already have dissolved solids in your water so your ec isn't a great representation of what's in your water. Im not going to be able to tell you what's lacking if anything, I think your rootzone is out of balance and unable to take up certain things. You said your water is relatively soft which means it's got salts in it, so if you only go by electric conductivity, it does take into account for what's in there but you don't know WHAT that is. Tap water has a lot of stuff in it.
Heres a chart that shows all the interactions of nutrients and how the balance of each effects others. And remember ph effects this too. Too high and too low some of these nutrients will not be taken up at all.
View attachment 1737860
As far as soil ph, get equal parts distilled water and a sample of soil, mix them together in a clean glass or jar, wait for the soil to settle on the bottom and ph the water left on top, that will give you an idea of what your soil ph is at. It's called a slurry test. But you want the sample to be as close to the root zone as possible. If I do it I go like 2 inches down at the edge of the pot. Also I hardly ever add calcium to my grows. I use spring water from a natural spring close to me. It's ppms are usually 90-150 so I already dial back my nutrients by a bit. I know from the water report theres already plenty of calcium and magnesium in my water so its readily available every time I water even with no food, but at the start of flower I will add a quarter dose as the nutrient balance shifts a little bit. You can see in the chart as the plant wants more phosphorus and potassium it effects pretty much everything else.