I test runoff by pHing my solution to something middle of the road like 6.5. Then I water until I get drops coming out of the drainage holes, and I collect that fluid and test it. I think the first drops are most accurate as they show you exactly what affect the soil has on the water, but the more that comes out you're going to naturally see it drift towards the same pH as the water coming in. I use a small pitcher and I know roughly how much each pot takes before it starts draining, so it's pretty easy to do all this. If I watered with 6.5 and my runoff was 6.3, I'd figure that my soil pH is somewhere around 6.2. So the next time if I want to bring that up I may water with 6.7 until my runoff comes up to exactly where I want it. It'll move around some depending on the plant and what stage of growth it's in, but you can keep it within range fairly easily with some practice.