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69 day old auto. only one leaf with the symptom. looks like dirt, maybe even frass, but upon closer inspection, not really any of the two.

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Suspected Ca lockout from too much N and Mg. Correcting slowly by feeding 1/5th strength nutes at low-end of the pH scale.
 

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Not a plant deficiencies but a pest
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Oh wow a cut worm! I was not even thinking along those lines. There is a whole army of pests and friendlies outdoors. Indoors not so much.

Thanks for the great addition to the effort. I am obtaining some ION meters which over time will allow me to document many nutrient metrics. By then I hope to have enough original photographs to put something together.
 
iron zinc problem
Not a problem just a cool leaf I thought this is lemon pie auto from fastbuds
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