Clix- the carbonates (CO3--) aren't involved with anything but pH buffering in solution, the plant doesn't use this anion; true, too much N and Mg can interfere with P uptake, but the levels would have to be really high, exactly
how high, IDK,... I see zero P defc, symptoms, in any case,... Mg defc. will affect lower leaves first, not uppers,.... looking at your pics in Weds. post, I can't see Ca defc. symptoms, though i do see some of the pale patches,... early symptoms can overlap with severeal other things, so I can't make a call yet, unless you have fresh pics of affected leaves,... post some please, and look at Ca defc. symptoms here, and see if it looks similar,--
https://www.autoflower.org/index.ph...irty-deficiency-picture-depot-expanded.43164/
.... another possible defc. hitting leaves up that high is Zn, which is also an immobile nute, so look that up as well,...
...watering with pure RO/DI water is okay, but you'll need Ca-Mg every time when doing it,... this water is stripped of everythuing, including the buffering Ca/Mg carbonates; without any hardness to the water (like tap has), even small input will cause wild pH swings, making the pH very unstable,... so, many folks blend their RO/DI water with dechlorinated tap,... something around 150ppm is good, still fairly soft, but has sufficient buffering capacity to make stable solutions,...
..dolomite lime (and the others, Ag and oyster too-?) won't force the pH above 7.0, but lots of it will have powerful buffering effects, making it difficult to make acidic soln.'s,.... dolomite is very slow acting too, BTW, compared to Ag and oyster shell,... it's slightly chemically different, still a Ca/Mg carbonate, but bonded differently,... as such it's better for long term pH buffering and slow nutrient release,... Ca-Phosphate is variable in solubility, depending on temp., and the form it is in,... the curling sure looks like the overwtaering type, not N-tox, and you say that's corrected now, right? ... Aaaand of course, pH affects all of this directly,.. what pH are you reading, and what method are you using to measure it? Coco like to be in the low 6's, according to most coco-nuts,...
This where I got my info about carbonate have No clue if its valid I have a link to the page though. I m just taking new pics now they still kinda suck but a new color has showed up red to purple on edges and between veins lol hope pics show it.
What Salts to Use
Macro Elements
Nitrogen
Recommended sources
Calcium Nitrate (15.5% N): Commercial calcium nitrate also forms 1% Ammonium-N in solution, and supplies 20%
Calcium
Potassium Nitrate (13% N): Also supplies 36.5% Potassium
Ammonium Nitrate (33% N): Nitrogen form is split between ammonium-N and Nitrate-N, the total ammonium-N % of a
formula should be kept below 15% in most conditions.
Other sources:
Ammonium Phosphate (10%N): Supplies N and is soluble, but all N is in the ammonium form, which limits its appli-cation
in hydroponics.
Ammonium Sulfate (21%N): As above, redundant if using conventional salts. Urea (46%N): Can cause problems with
ammonia toxicity, and has no CF charge so difficult to measure.
Nitric Acid: Used often for pH control, but should not be considered a nitrogen source, especially not mixed with salts
in stock solutions.
Phosphorus
Recommended Sources
MonoPotassium Phosphate (21% P): Also provides 25% Potassium.
Other sources:
Ammonium Phosphate (22% P): Not used as the main phosphate source as too much ammonium would be produced.
Phosphoric Acid: As for Nitric acid above. Older formulations used it as a P source in 'Topping-up" mixtures but this
approach is no longer valid.
Calcium Superphosphate (10% P): Phosphate is highly soluble (as phosphoric acid), but produces an insoluble
calcium sulfate / calcium phosphate residue in hydroponics.
Potassium
Recommended Sources
Potassium Nitrate (37% K)
MonoPotassium Phosphate (25% K)
Potassium Sulfate (40% K): Also adds sulfur (17%). Useful as an additive to existing formulae to boost potassium
levels.
Other sources:
Potassium Chloride (49% K): Can be added in small amounts, although preferably omitted due to its chloride content.
Magnesium
Recommended sources
Magnesium Sulfate (10% Mg): Also adds sulfur. Is highly soluble and universal Mg source
Other sources:
Magnesium Nitrate Expensive, and unnecessary
Dolomite (Magnesium carbonate) Insoluble residues
Fertiliser sources of magnesium used in agriculture (Dolomite, Causmag etc) are generally very insoluble, and can not
be used for hydroponics.
Calcium
Recommended sources
Calcium Nitrate (20% Ca): Calcium is supplied almost entirely by this salt in most nutrient formulations
Calcium Chloride (36% Ca): Useful to add extra calcium without altering other elements. Limited use due to its
chloride content, so only used as an 'additive'
Other sources:
Calcium chelates: Expensive and unnecessary
Calcium Ammonium Nitrate: Not recommended due to ammonia content
Calcium cyanamide: Release amine - N into solution which produces free ammonia.
Calcium carbonate: Insoluble, and inherent pH problems
Calcium Sulfate: Highly insoluble.
Sulfur
Recommended sources
Magnesium sulfate (13% S): Potassium sulfate (18% S)
Other sources:
Ammonium sulfate
Sulfuric acid
Trace Elements
Iron
Recommended sources
Iron EDTA (6 - 14% Fe): Readily soluble, and stable form of Iron for nutrient solutions. Ensure the element (Fe)
content of the chelate is known before making formulations.
Iron EPTA: Using different chelating agents the iron can be protected in solution at higher pH levels.
Iron EDDHA " " "
Other sources:
Iron Sulfate (20% Fe): No longer widely used in hydroponics due to its instability in solution. In nutrient solutions iron
sulfate tends to form iron hydroxides which are insoluble.
Iron Chloride: As above
Manganese
Recommended sources
Manganese Sulfate (24%): Different sources may vary in Mn% due to being hydrated or anhydrous. In solution with
Iron EDTA, the manganese becomes partly chelated.
Manganese Chelate (*%): As for Fe EDTA * the content of Mn can vary between sources.
Boron
Recommended sources
Boric Acid (18% B), Sodium borate (Borax) 11 - 14% B
Zinc
Recommended sources
Zinc Sulfate (23% Zn), Zinc EDTA (*%)
Copper
Recommended sources
Copper Sulfate (25% Cu), Copper EDTA (*%)
Molybdenum
Recommended sources
Ammonium molybdate (48% Mo), Sodium Molybdate (39% Mo)