I don't think there will be an issue with smoking plants treated with it. Seems it's metabolized by the plant regardless if fed through soil or foliar.
Here's some info I found "The exogenous application of L-TRP is highly significant for normal plant growth and development. L-tryptophan is applied through foliar spray, seed priming, and soil application. Soil-applied L-TRP is either directly taken up by plants or metabolized to auxin by soil microbiota and then absorbed by plant roots. Similarly, foliar spray and seed priming with L-TRP stimulates auxin synthesis within plants and improves the growth and productivity of agricultural crops. Furthermore, L-TRP contains approximately 14% nitrogen (N) in its composition, which is released upon its metabolism within a plant or in the rhizosphere and plays a role in enhancing crop productivity."
Also we will only be using it in veg anyhow.....any of it still around will have been metabolized.
I found a couple studies about it used in agriculture (which is where that quote came from) to increase yield and 1 that touched on it's use in tobacco but no details.